Mark Meijerink

PhD Candidate
Employed since: October 2015
Phone: +316 48261826
Room: 4th floor study area



Advanced electron microscopy for understanding supported metal catalyst synthesis
Since the advent of industrial catalysis, many investigations focus on the development of new recipes or improvement of known recipes for catalyst synthesis with relatively little understanding of the physics and chemistry governing the processes involved. This is clearly illustrated in the development of catalysts for one of the most famous and important chemical processes in history, the Haber-Bosch process for the synthesis of ammonia from hydrogen and nitrogen. To develop a catalyst for this process, Haber tested hundreds of different catalysts and took the one with the best performance.

Although this is a possibility for the development of new catalysts, it is relatively slow, expensive and only yields limited understanding of the processes involved. Therefore this project aims to improve the understanding of supported metal catalyst synthesis in a liquid phase. It is already known that performance of such catalysts is dependent on many different factors, chief among which are metal nanoparticle size, spatial distribution and interaction of nanoparticles with the support.

Recent developments in Transmission Electron Microscopy (TEM), including tomography and liquid phase TEM allow for 3D imaging of nanostructures or imaging of dynamic processes at nanoscale in a liquid respectively. This allows for obtaining an unprecedented understanding of relevant processes, such as nanoparticle formation or movement occurring during the synthesis of supported metal catalysts.

The liquid phase TEM will therefore be used to monitor the formation of gold and platinum nanoparticles from precursor solutions on both model supports and industrially relevant supports, with a focus on silica and zeolite supports. Ex situ experiments are also performed to pinpoint possible influences of the electron beam and compare observed data to averages of larger volumes of catalyst. By studying these phenomena and how they are influenced by synthesis and support parameters, better control over catalyst manufacture and improved catalyst design can be achieved.

Figure 1: Schematic representation of liquid phase TEM, with a thin microchip containing the liquid, allowing the electron beam to travel through the sample [1]



Figure 2: Reconstructed 3D image prepared by electron tomography, highlighting the inhomogeneous distribution of Pt in a zeolite Y support [2].

[1] N. de Jonge, F.M. Ross, Nature Nanotechnology 6, 695-704 (2011)
[2] J. Zecevic, A.M.J. van der Eerden, H. Friedrich, P.E. de Jongh, K.P. de Jong, ACS Nano 7, 3698-3705 (2013)





PhD candidate under supervision of Prof. dr. ir. Krijn de Jong in the group of Inorganic Chemistry and Catalysis, Utrecht University, the Netherlands. This project is sponsored by an ERC grant
“Advanced electron microscopy for improved understanding of supported metal catalyst synthesis.”

4 months internship at Yokohama, National University, Japan
Project: “Understanding of the healing mechanism in Al2O3/TiC self-healing composites by SEM-FIB.”

Double degree in Chemical Engineering and Materials Science & Engineering at Delft, University of Technology
Specialization Chemical Engineering: Process Engineering
Specialization Materials Science & Engineering: Metals science and high temperature materials
Thesis: “Coating of MoSi2 healing particles for self-healing thermal barrier coatings.” (combined master thesis)

7 months minor in materials science at Politecnico di Milano, Italy

Bachelor Molecular Science & Technology, joint degree of Delft University of Technology and Leiden University.Specialization: Process engineering
Thesis: “Bifunctional hierarchical zeolite supported cobalt catalysts for Fischer-Tropsch synthesis.”

Gymnasium, Hermann Wesselink College, Amstelveen, The Netherlands


Meijerink, M J; Jong, De K P; Zečević, J

Growth of Supported Gold Nanoparticles in Aqueous Phase Studied by in Situ Transmission Electron Microscopy Journal Article

Journal of Physical Chemistry C, 124 (3), pp. 2202-2212, 2020, (cited By 1).

Links | BibTeX

Meijerink, M J; de Jong, K P; Zečević, J

Assessment of oxide nanoparticle stability in liquid phase transmission electron microscopy Journal Article

Nano Research, 12 (9), pp. 2355-2363, 2019, (cited By 1).

Links | BibTeX

Meijerink, M J; Spiga, C; Hansen, T W; Damsgaard, C D; de Jong, K P; Zečević, J

Nanoscale Imaging and Stabilization of Silica Nanospheres in Liquid Phase Transmission Electron Microscopy Journal Article

Particle and Particle Systems Characterization, 36 (1), 2019, (cited By 1).

Links | BibTeX

Sun, X; Suarez, A I O; Meijerink, M J; Deelen, Van T; Ould-Chikh, S; Zečević, J; Jong, De K P; Kapteijn, F; Gascon, J

Manufacture of highly loaded silica-supported cobalt Fischer-Tropsch catalysts from a metal organic framework Journal Article

Nature Communications, 8 (1), 2017, (cited By 16).

Links | BibTeX