Research
Nanoconfined complex hydrides as fast ion conductors for rechargeable batteries
The development of efficient energy storage systems is a key ingredient to facilitate wide-spread use of energy from renewable sources like solar and wind. A promising option is the use of high energy density rechargeable batteries. One of the major obstacles to realizing such high energy density batteries is the development of solid state fast ion conductors needed to realize all solid state rechargeable cells [1]. The light-weight complex hydrides especially those based on Li and Na have recently attracted significant attention as promising electrolyte materials for all solid-state Li and Na ion batteries [2]. Unfortunately these materials do not show sufficient ionic conductivity at ambient temperatures which is required for most battery applications.
It was recently discovered that the Li-ion conductivity of the complex hydride LiBH4 can be increased by about three orders of magnitude at room temperature when nanoconfined in mesoporous silica scaffolds [3-4]. The exact origin of this effect is not clear yet but is related to enhance Li-ion mobility resulting from possible interaction between LiBH4 and silica pore walls in the nanocomposites. The major aim of this project is to obtain a profound understanding of the origin of the increase conductivity upon nanoconfinement, and how this can be optimized to realize stable and high energy density all-solid state rechargeable batteries. The effects of nanoconfinement on the ionic conductivity of Li, Na, Mg and Al based complex hydrides will be investigated using different nanoscaffold materials.
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C.V.
2015-present:
Postdoctoral research fellow in the group of Prof. Petra. E. de Jongh, Inorganic Chemistry and Catalysis, Utrecht University, The Netherlands
2012-2014:
Postdoctoral Research fellow, Prof Bernard Dam’s group, Materials for Energy conversion and Storage (MECS), Chemical Engineering Department, Delft University of Technology, Netherland
Research Topic: Development of metal and polymer composite thin films/membranes for energy storage, hydrogen sensing and gas separation
2007-2011:
PhD, Inorganic Chemistry and Catalysis, Utrecht University. Supervisors: Prof. Petra de Jongh and Prof. dr. ir. Krijn de Jong
Thesis title: Nanoconfined complex metal hydrides for reversible hydrogen storage
2006-2007:
MSc (MEMS) Micro- and Nano-Systems Engineering, ESIEE- Paris and Nanyang Technological University (NTU) Singapore
Thesis title: Novel metal borohydrides for reversible hydrogen storage
2003-2005:
Process Engineer, Dangote Sugar Refinery, Lagos Nigeria
1997-2002:
B.Sc. Hons. Degree in Chemical Engineering, Federal University of technology Owerri (FUTO), Nigeria
Hirscher, M; Yartys, V A; Baricco, M; von Colbe, J Bellosta; Blanchard, D; Bowman, R C; Broom, D P; Buckley, C E; Chang, F; Chen, P; Cho, Y W; Crivello, J -C; Cuevas, F; David, W I F; de Jongh, P E; Denys, R V; Dornheim, M; Felderhoff, M; Filinchuk, Y; Froudakis, G E; Grant, D M; Gray, E M; Hauback, B C; He, T; Humphries, T D; Jensen, T R; Kim, S; Kojima, Y; Latroche, M; Li, H -W; Lototskyy, M V; Makepeace, J W; Møller, K T; Naheed, L; Ngene, P; Noréus, D; Nygård, M M; Orimo, S -I; Paskevicius, M; Pasquini, L; Ravnsbæk, D B; Sofianos, M Veronica; Udovic, T J; Vegge, T; Walker, G S; Webb, C J; Weidenthaler, C; Zlotea, C
Materials for hydrogen-based energy storage – past, recent progress and future outlook Journal Article
In: Journal of Alloys and Compounds, vol. 827, 2020, (cited By 4).
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Zettl, R; Kort, L De; Gombotz, M; Wilkening, H M R; Jongh, P E De; Ngene, P
Combined Effects of Anion Substitution and Nanoconfinement on the Ionic Conductivity of Li-Based Complex Hydrides Journal Article
In: Journal of Physical Chemistry C, vol. 124, no. 5, pp. 2806-2816, 2020, (cited By 1).
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url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85080143991&doi=10.1021%2facs.jpcc.9b10607&partnerID=40&md5=7cfc6d459e93c99b577472ac3c3899eb},
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Chang, F; Wu, H; Pluijm, R V D; Guo, J; Ngene, P; Jongh, P E De
Effect of Pore Confinement of NaNH<inf>2</inf> and KNH<inf>2</inf> on Hydrogen Generation from Ammonia Journal Article
In: Journal of Physical Chemistry C, vol. 123, no. 35, pp. 21487-21496, 2019, (cited By 0).
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url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85072339903&doi=10.1021%2facs.jpcc.9b03878&partnerID=40&md5=180a469b04b4f1495e00f67246b3a694},
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Makepeace, J W; He, T; Weidenthaler, C; Jensen, T R; Chang, F; Vegge, T; Ngene, P; Kojima, Y; de Jongh, P E; Chen, P; David, W I F
Reversible ammonia-based and liquid organic hydrogen carriers for high-density hydrogen storage: Recent progress Journal Article
In: International Journal of Hydrogen Energy, vol. 44, no. 15, pp. 7746-7767, 2019, (cited By 7).
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author = {J W Makepeace and T He and C Weidenthaler and T R Jensen and F Chang and T Vegge and P Ngene and Y Kojima and P E de Jongh and P Chen and W I F David},
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Latroche, M; Blanchard, D; Cuevas, F; Kharbachi, A El; Hauback, B C; Jensen, T R; de Jongh, P E; Kim, S; Nazer, N S; Ngene, P; Orimo, S -I; Ravnsbæk, D B; Yartys, V A
Full-cell hydride-based solid-state Li batteries for energy storage Journal Article
In: International Journal of Hydrogen Energy, vol. 44, no. 15, pp. 7875-7887, 2019, (cited By 6).
@article{Latroche20197875,
title = {Full-cell hydride-based solid-state Li batteries for energy storage},
author = {M Latroche and D Blanchard and F Cuevas and A El Kharbachi and B C Hauback and T R Jensen and P E de Jongh and S Kim and N S Nazer and P Ngene and S -I Orimo and D B Ravnsbæk and V A Yartys},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85060860021&doi=10.1016%2fj.ijhydene.2018.12.200&partnerID=40&md5=0ac4730fbbcba4d14f33e274bb7564ff},
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Milanese, C; Jensen, T R; Hauback, B C; Pistidda, C; Dornheim, M; Yang, H; Lombardo, L; Zuettel, A; Filinchuk, Y; Ngene, P; de Jongh, P E; Buckley, C E; Dematteis, E M; Baricco, M
Complex hydrides for energy storage Journal Article
In: International Journal of Hydrogen Energy, vol. 44, no. 15, pp. 7860-7874, 2019, (cited By 19).
@article{Milanese20197860,
title = {Complex hydrides for energy storage},
author = {C Milanese and T R Jensen and B C Hauback and C Pistidda and M Dornheim and H Yang and L Lombardo and A Zuettel and Y Filinchuk and P Ngene and P E de Jongh and C E Buckley and E M Dematteis and M Baricco},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85059224737&doi=10.1016%2fj.ijhydene.2018.11.208&partnerID=40&md5=1ee6780ca0a7839327959abe3ae71286},
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Lambregts, S F H; Eck, E R H Van; Suwarno,; Ngene, P; Jongh, P E De; Kentgens, A P M
Phase Behavior and Ion Dynamics of Nanoconfined LiBH<inf>4</inf> in Silica Journal Article
In: Journal of Physical Chemistry C, vol. 123, no. 42, pp. 25559-25569, 2019, (cited By 0).
@article{Lambregts201925559,
title = {Phase Behavior and Ion Dynamics of Nanoconfined LiBH<inf>4</inf> in Silica},
author = {S F H Lambregts and E R H Van Eck and Suwarno and P Ngene and P E De Jongh and A P M Kentgens},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073432205&doi=10.1021%2facs.jpcc.9b06477&partnerID=40&md5=9e288165249b3ed895c6fdb4250d85d0},
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Ngene, P; Lambregts, S F H; Blanchard, D; Vegge, T; Sharma, M; Hagemann, H; Jongh, P E De
The influence of silica surface groups on the Li-ion conductivity of LiBH<inf>4</inf>/SiO<inf>2</inf> nanocomposites Journal Article
In: Physical Chemistry Chemical Physics, vol. 21, no. 40, pp. 22456-22466, 2019, (cited By 0).
@article{Ngene201922456,
title = {The influence of silica surface groups on the Li-ion conductivity of LiBH<inf>4</inf>/SiO<inf>2</inf> nanocomposites},
author = {P Ngene and S F H Lambregts and D Blanchard and T Vegge and M Sharma and H Hagemann and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85073483170&doi=10.1039%2fc9cp04235k&partnerID=40&md5=d804cb8abd9ca084161385e6cf47e488},
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Bramwell, P L; Ngene, P; de Jongh, P E
Carbon supported lithium hydride nanoparticles: Impact of preparation conditions on particle size and hydrogen sorption Journal Article
In: International Journal of Hydrogen Energy, vol. 42, no. 8, pp. 5188-5198, 2017, (cited By 7).
@article{Bramwell20175188,
title = {Carbon supported lithium hydride nanoparticles: Impact of preparation conditions on particle size and hydrogen sorption},
author = {P L Bramwell and P Ngene and P E de Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85003458955&doi=10.1016%2fj.ijhydene.2016.10.062&partnerID=40&md5=07f9caf10dbdfcc3c45baf6a887f84f4},
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Suwarno,; Ngene, P; Nale, A; Eggenhuisen, T M; Oschatz, M; Embs, J P; Remhof, A; Jongh, P E De
Confinement Effects for Lithium Borohydride: Comparing Silica and Carbon Scaffolds Journal Article
In: Journal of Physical Chemistry C, vol. 121, no. 8, pp. 4197-4205, 2017, (cited By 6).
@article{Suwarno20174197,
title = {Confinement Effects for Lithium Borohydride: Comparing Silica and Carbon Scaffolds},
author = {Suwarno and P Ngene and A Nale and T M Eggenhuisen and M Oschatz and J P Embs and A Remhof and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015178197&doi=10.1021%2facs.jpcc.6b13094&partnerID=40&md5=c43d7a39a831c89c1d0b25982e3a3b1c},
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Das, S; Ngene, P; Norby, P; Vegge, T; Jongh, P E De; Blanchard, D
All-solid-state lithium-sulfur battery based on a nanoconfined LiBH4 electrolyte Journal Article
In: Journal of the Electrochemical Society, vol. 163, no. 9, pp. A2029-A2034, 2016, (cited By 22).
@article{Das2016A2029,
title = {All-solid-state lithium-sulfur battery based on a nanoconfined LiBH4 electrolyte},
author = {S Das and P Ngene and P Norby and T Vegge and P E De Jongh and D Blanchard},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84982732967&doi=10.1149%2f2.0771609jes&partnerID=40&md5=965268c4b19c9170ef0cab353439a66d},
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year = {2016},
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note = {cited By 22},
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Ngene, P; Verkuijlen, M H W; Barre, C; Kentgens, A P M; de Jongh, P E
Reversible Li-insertion in nanoscaffolds: A promising strategy to alter the hydrogen sorption properties of Li-based complex hydrides Journal Article
In: Nano Energy, vol. 22, pp. 169-178, 2016, (cited By 10).
@article{Ngene2016169,
title = {Reversible Li-insertion in nanoscaffolds: A promising strategy to alter the hydrogen sorption properties of Li-based complex hydrides},
author = {P Ngene and M H W Verkuijlen and C Barre and A P M Kentgens and P E de Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84958749071&doi=10.1016%2fj.nanoen.2016.02.003&partnerID=40&md5=cac3e0f4e1ae37baff2d435c48b405e8},
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Bramwell, P L; Lentink, S; Ngene, P; Jongh, P E De
Effect of Pore Confinement of LiNH2 on Ammonia Decomposition Catalysis and the Storage of Hydrogen and Ammonia Journal Article
In: Journal of Physical Chemistry C, vol. 120, no. 48, pp. 27212-27220, 2016, (cited By 5).
@article{Bramwell201627212,
title = {Effect of Pore Confinement of LiNH2 on Ammonia Decomposition Catalysis and the Storage of Hydrogen and Ammonia},
author = {P L Bramwell and S Lentink and P Ngene and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85003456343&doi=10.1021%2facs.jpcc.6b10688&partnerID=40&md5=a4608095f3fa4f416a6ea13166bfd245},
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Delmelle, R; Ngene, P; Dam, B; Bleiner, D; Borgschulte, A
Promotion of Hydrogen Desorption from Palladium Surfaces by Fluoropolymer Coating Journal Article
In: ChemCatChem, vol. 8, no. 9, pp. 1646-1650, 2016, (cited By 6).
@article{Delmelle20161646,
title = {Promotion of Hydrogen Desorption from Palladium Surfaces by Fluoropolymer Coating},
author = {R Delmelle and P Ngene and B Dam and D Bleiner and A Borgschulte},
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Gao, J; Ngene, P; Herrich, M; Xia, W; Gutfleisch, O; Muhler, M; Jong, K P De; Jongh, P E De
Interface effects in NaAlH4-carbon nanocomposites for hydrogen storage Journal Article
In: International Journal of Hydrogen Energy, vol. 39, no. 19, pp. 10175-10183, 2014, (cited By 10).
@article{Gao201410175,
title = {Interface effects in NaAlH4-carbon nanocomposites for hydrogen storage},
author = {J Gao and P Ngene and M Herrich and W Xia and O Gutfleisch and M Muhler and K P De Jong and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84901926083&doi=10.1016%2fj.ijhydene.2014.03.188&partnerID=40&md5=cc44b65a40e08ccdf7958791fc155bb3},
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number = {19},
pages = {10175-10183},
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Miedema, P S; Ngene, P; Eerden, A M J Van Der; Sokaras, D; Weng, T -C; Nordlund, D; Au, Y S; Groot, F M F De
In situ X-ray Raman spectroscopy study of the hydrogen sorption properties of lithium borohydride nanocomposites Journal Article
In: Physical Chemistry Chemical Physics, vol. 16, no. 41, pp. 22651-22658, 2014, (cited By 8).
@article{Miedema201422651,
title = {In situ X-ray Raman spectroscopy study of the hydrogen sorption properties of lithium borohydride nanocomposites},
author = {P S Miedema and P Ngene and A M J Van Der Eerden and D Sokaras and T -C Weng and D Nordlund and Y S Au and F M F De Groot},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84907513103&doi=10.1039%2fc4cp02918f&partnerID=40&md5=a72614d9bab7f898a43ba5a01aae4355},
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Remhof, A; Mauron, P; Züttel, A; Embs, J P; Łodziana, Z; Ramirez-Cuesta, A J; Ngene, P; Jongh, P De
Hydrogen dynamics in nanoconfined lithiumborohydride Journal Article
In: Journal of Physical Chemistry C, vol. 117, no. 8, pp. 3789-3798, 2013, (cited By 37).
@article{Remhof20133789,
title = {Hydrogen dynamics in nanoconfined lithiumborohydride},
author = {A Remhof and P Mauron and A Züttel and J P Embs and Z Łodziana and A J Ramirez-Cuesta and P Ngene and P De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84874613847&doi=10.1021%2fjp311064d&partnerID=40&md5=4b6f04479c3b8471920b4ef17db41296},
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Miedema, P S; Ngene, P; Eerden, A M J Van Der; Weng, T -C; Nordlund, D; Sokaras, D; Alonso-Mori, R; Juhin, A; Jongh, P E De; Groot, F M F De
In situ X-ray Raman spectroscopy of LiBH 4 Journal Article
In: Physical Chemistry Chemical Physics, vol. 14, no. 16, pp. 5581-5587, 2012, (cited By 11).
@article{Miedema20125581,
title = {In situ X-ray Raman spectroscopy of LiBH 4},
author = {P S Miedema and P Ngene and A M J Van Der Eerden and T -C Weng and D Nordlund and D Sokaras and R Alonso-Mori and A Juhin and P E De Jongh and F M F De Groot},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84859361769&doi=10.1039%2fc2cp24025d&partnerID=40&md5=24246a04707d9ae2ba062d5f330c6d4f},
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Gao, J; Ngene, P; Lindemann, I; Gutfleisch, O; Jong, K P De; Jongh, P E De
Enhanced reversibility of H 2 sorption in nanoconfined complex metal hydrides by alkali metal addition Journal Article
In: Journal of Materials Chemistry, vol. 22, no. 26, pp. 13209-13215, 2012, (cited By 25).
@article{Gao201213209,
title = {Enhanced reversibility of H 2 sorption in nanoconfined complex metal hydrides by alkali metal addition},
author = {J Gao and P Ngene and I Lindemann and O Gutfleisch and K P De Jong and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84862532998&doi=10.1039%2fc2jm31064c&partnerID=40&md5=e90c7450bbfcff23d1744fda0b585b12},
doi = {10.1039/c2jm31064c},
year = {2012},
date = {2012-01-01},
journal = {Journal of Materials Chemistry},
volume = {22},
number = {26},
pages = {13209-13215},
note = {cited By 25},
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Verkuijlen, M H W; Ngene, P; Kort, D W De; Barré, C; Nale, A; Eck, E R H Van; Bentum, P J M Van; Jongh, P E De; Kentgens, A P M
Nanoconfined LiBH 4 and enhanced mobility of Li +and BH 4 - studied by solid-state NMR Journal Article
In: Journal of Physical Chemistry C, vol. 116, no. 42, pp. 22169-22178, 2012, (cited By 48).
@article{Verkuijlen201222169,
title = {Nanoconfined LiBH 4 and enhanced mobility of Li +and BH 4 - studied by solid-state NMR},
author = {M H W Verkuijlen and P Ngene and D W De Kort and C Barré and A Nale and E R H Van Eck and P J M Van Bentum and P E De Jongh and A P M Kentgens},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84867843258&doi=10.1021%2fjp306175b&partnerID=40&md5=6a4562e504ff6b3b389b0350321a7745},
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Ngene, P; Verkuijlen, M H W; Zheng, Q; Kragten, J; Bentum, P J M Van; Bitter, J H; Jongh, P E De
The role of Ni in increasing the reversibility of the hydrogen release from nanoconfined LiBH4 Journal Article
In: Faraday Discussions, vol. 151, pp. 47-58, 2011, (cited By 49).
@article{Ngene201147,
title = {The role of Ni in increasing the reversibility of the hydrogen release from nanoconfined LiBH4},
author = {P Ngene and M H W Verkuijlen and Q Zheng and J Kragten and P J M Van Bentum and J H Bitter and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-80051589646&doi=10.1039%2fc0fd00028k&partnerID=40&md5=923e68a4b27620660e6cea27fad14dd1},
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Ngene, P; Berg, R Van Den; Verkuijlen, M H W; Jong, K P De; Jongh, P E De
Reversibility of the hydrogen desorption from NaBH 4 by confinement in nanoporous carbon Journal Article
In: Energy and Environmental Science, vol. 4, no. 10, pp. 4108-4115, 2011, (cited By 65).
@article{Ngene20114108,
title = {Reversibility of the hydrogen desorption from NaBH 4 by confinement in nanoporous carbon},
author = {P Ngene and R Van Den Berg and M H W Verkuijlen and K P De Jong and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-80053310202&doi=10.1039%2fc1ee01481a&partnerID=40&md5=74ecd068225fd3fe939560a54d6c1946},
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Ngene, P; Adelhelm, P; Beale, A M; Jong, K P De; Jongh, P E De
LiBH4/SBA-15 nanocomposites prepared by melt infiltration under hydrogen pressure: Synthesis and hydrogen sorption properties Journal Article
In: Journal of Physical Chemistry C, vol. 114, no. 13, pp. 6163-6168, 2010, (cited By 96).
@article{Ngene20106163,
title = {LiBH4/SBA-15 nanocomposites prepared by melt infiltration under hydrogen pressure: Synthesis and hydrogen sorption properties},
author = {P Ngene and P Adelhelm and A M Beale and K P De Jong and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-77950578753&doi=10.1021%2fjp9065949&partnerID=40&md5=9f1b53c56404ccd4d8ec2462639485a7},
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year = {2010},
date = {2010-01-01},
journal = {Journal of Physical Chemistry C},
volume = {114},
number = {13},
pages = {6163-6168},
note = {cited By 96},
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Ngene, P; Zwienen, R Van; Jongh, P E De
Reversibility of the hydrogen desorption from LiBH4: A synergetic effect of nanoconfinement and Ni addition Journal Article
In: Chemical Communications, vol. 46, no. 43, pp. 8201-8203, 2010, (cited By 98).
@article{Ngene20108201,
title = {Reversibility of the hydrogen desorption from LiBH4: A synergetic effect of nanoconfinement and Ni addition},
author = {P Ngene and R Van Zwienen and P E De Jongh},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-77958490615&doi=10.1039%2fc0cc03218b&partnerID=40&md5=13eb2130806450542e8ae4281b14305e},
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Other publications
See earlier publications on Scopus.